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Sunday, 23 November 2014 00:00

26. Oxidoreductive Coupling of Thiols with Aryl Halides Catalyzed by Copper on Iron

Oxidoreductive Coupling of Thiols with Aryl Halides Catalyzed by Copper on Iron, Szabolcs Kovács, Zoltán Novák, Org. Biomol. Chem. 2011, 9, 711-716. DOI: 10.1039/C0OB00397B | [Supp. Info Link]

Synthesis and utilization of a simple copper on iron catalyst in the coupling of aryl halides with thiols through disulfide intermediate is reported. The iron support of copper catalyst ensures reductive media for the coupling, allows easy removal of the metals by outer magnetic field and enables the recycling of the catalyst.

zng pub 26