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Sunday, 10 September 2017 14:04

62. Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts

Copper-Catalyzed N-Arylation of Nitroenamines with Diaryliodonium Salts, Klára Aradi, Ádám Mészáros, Balázs László Tóth, Zoltán Vincze, Zoltán Novák, J. Org. Chem. 2017, ASAP. DOI: 10.1021/acs.joc.7b01591 | [Full Text Link] [Supp. Info. Link]

A novel synthetic methodology was developed for the N-arylation of nitroenamine derivatives utilizing diaryliodonium triflates and copper (I) chloride as a catalyst. The procedure enables the ease aryl transfer from the hypervalent species under mild catalytic conditions with unusual heteroatom preference and high efficiency.

zng pub 62